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Ali Munawar
Faculty of Agriculture, UPN “Veteran” Yogyakarta

Professor of Soil Science

Djoko Mulyanto
Faculty of Agriculture, UPN “Veteran” Yogyakarta

RR Dina Asrifah
Faculty of Mineral Engineering, UPN “Veteran” Yogyakarta

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Equilibrium studies for the removal of manganese (Mn) from aqueous solution using natural zeolite from West Java, Indonesia

Ali Munawar, Djoko Mulyanto, RR Dina Asrifah
  J. Degrade. Min. Land Manage. , pp. 4191-4198  
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Manganese (Mn) is one of the heavy metals found in industrial wastewater, such as acid mine drainage, which has caused serious environmental problems worldwide. This equilibrium study was carried out to determine the maximum capacity of natural zeolite towards manganese removal from made aqueous solution as affected by zeolite quantity, particle size, activation temperature, and initial pH of the solution. The natural zeolites obtained from Tasikmalaya, West Java, Indonesia, were crushed and filtered into three groups of diameters: <0.5, 1-2, and 2-4 mm. Each group was divided into two sub-groups, one sub-group was heated in a muffle furnace at 250 oC for two hours, and the other sub-group was left at room temperature (25 oC). This experiment consisted of two sections. Section one was physical and chemical characterizations of the natural zeolite, using Scanning Electron Microscopy (SEM), X-Ray Diffraction, and X-Ray Fluorescence techniques. The second section was equilibrium studies using two series of 0.5, 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, and 5 g of natural zeolites of each sub-groups, then respectively added with 50 mL of a solution containing 50 ppm Mn having pH of 5.5 and 7.0. All suspensions were shaken for 24 h and filtered. The filtrates were red for total dissolved Mn using Atomic Adsorption Spectrophotometer (AAS). Freundlich and Langmuir isothermic models were fitted to the collected data to describe the adsorptive behaviour of Mn toward natural zeolites. Data showed that 0.5 g of natural zeolite had removed the remarkably highest Mn from the solution, regardless of the size of the particles, thermal treatment, and initial solution pH. The smallest size of zeolite particle and higher initial solution pH tended to increase the adsorptive capacity of the natural zeolite toward Mn. The Freundlich isothermic model fitted better to Mn adsorption behaviour than the Langmuir model.


isothermic models; manganese; natural zeolite; SEM; XRD; XRF

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Atikah, W.S. 2017. The potential of activated natural zeolite from Gunung Kidul as adsorbent to textile dyes. Arena Tekstil 32(1):17-27, doi:10.31266/at.v32i1.2650 (in Indonesian).

Ayawei, N., Ebelegi, A.N. and Wankasi, D. 2017. Modelling and interpretation of adsorption isotherms. Journal of Chemistry Article ID 3039817, 11 pages, doi:10.1155/2017/3039817.

Bakalár, T. and Pavolová, H. 2018. Removal of manganese from water using natural zeolite. International Journal of Engineering Research and Technology 11(12):2045-2059.

Belova, T.P. 2019. Adsorption of heavy metal ions (Cu2+, Ni2+, Co2+, and Fe2+) from aqueous solutions by natural zeolite. Heliyon 5(2019):eO2320, doi:10.1016/heliyon. 2019. e02320.

Chiban, M.Z., Crza, G. and Sina, F. 2012. Application of low-cost adsorbent for arsenic removal. Journal Environmental Chemistry Ecotoxicology 4:91-102, doi:10.5897/JECE11.013.

da Silveira, A.N., Silva, R. and Rubio, J. 2009. Treatment of acid mine drainage (AMD) in South Brazil: comparative active processes and water reuse. International Journal of Mineral Processing 93(2):103-109.

Dada, A.O., Olalekan, A.P., Olatunya, A.M. and Dada, O. 2012. Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherms studies of equilibrium sorption of Zn2+ unto phosphoric acid modified rice husk. IOSR Journal of Applied Chemistry 3(1):38-45.

Dewi, E.M., Suwardi, Suryaningtyas, D.T. and Anwar, S. 2016. Utilization of natural zeolite as Cu (Ii) and Zn (Ii) adsorbent. Journal of Tropical Soils 21(3):153-160, doi:10.5400/jts.2016.v21i3.153-160.

Erdem, E. Karapinar, N and Donat, R. 2004. The removal of heavy metal cations by natural zeolites. Journal of Colloid and Interface Science 280:309-314, doi:10.1016/j.jcis.2004.08.028.

Kadja, G.T.M. and Ilmi, M.M. 2019. Indonesia natural mineral for heavy metal adsorption: a review. Journal of Environmental Science and Sustainable Development 2(2):139-162, doi:10.7454/jessd.v212.1033

Krol, M. 2020. Natural vs synthetic zeolites. Crystals 10:622, doi:10.3390/cryst10070622.

Kusdarto. 2008. Potensi zeolit di Indonesia. Jurnal Zeolit Indonesia 7(2):78-87 (in Indonesian).

Kwakye-Awuah, B., Sefa-Ntiri, B., Von-Kiti, E., Nkumah, I. and Williams, C. 2019. Adsorptive removal of iron and manganese from groundwater samples in Ghana by zeolite Y synthesized from Bauxite and Kaolin. Water 11:2-19, doi:10.3390/w11091912.

Liu, S. 2015. Cooperative adsorption on solid surfaces. Journal of Colloid and Interface 450:224-238, doi:10.1016/j.jcis.2015.03.013.

Masoudian, S.K., Sadighi, S. and Abbasi, A. 2013. Synthesis and characterization of high aluminum zeolite X from technical grade materials. Bulletin of Chemical Reaction Engineering and Catalysts 8(1):54-60, doi:10.9767/bcrec.8.1.4321.54-60.

Munawar, A. Putranto, A.M.H. and Bertham, Y.H. 2017. Reducing acid mine drainage formation using locally-available soil ameliorants. Advanced Science Letters 23(3):2251-2253, doi:10.1166/ asl.2017.8746.

Murtihapsari, Mangallo, B, and Handayani, D.D. 2012. Freundlich and Langmuir isotherm model, by activated charcoal adsorbent bamboo Andong (G. vericillata (Wild) Munro) and bamboo Ater (G. attaer (Hassk) Kurz ex Munro). Jurnal Sains Natural Universitas Nusa Bangsa 2(1):17-12 (in Indonesian).

Neag, E., Torok, A.I., Tanaselia, C., Aschilean, I. and Senila, M. 2020. Kinetics and equilibrium studies for removal of Mn and Fe from binary metal solution systems using a Romanian thermally activated zeolite. Water 12:1614, doi:10.3390/ w12061614.

Omri, A. and Benzina, M. 2012. Removal of manganese (II) ions from aqueous solutions by adsorption on activated derived a new precursor: Ziziphus spinachristi seeds. Alexandria Engineering Journal 51:343-350, doi:10.1016/j.aej.2012.06.003.

Setiawan, I., Estiaty, L.M., Fatimah, D., Indarto, S., Lintjewas, L., Alkausar, A., Handoko, A.D., Yuliyanti, A. and Jakah. 2020. Geology and petrochemical zeolite deposits in Bayah and Sukabumi Areas. Riset Geologi dan Pertambangan 30(1):39-54, doi:10.14203/risetgeotam2020.v30.1048 (in Indonesian).

Taffarel, S.R. and Rubio, J. 2010. Removal of Mn2+ from aqueous solution by manganese oxide-coated zeolite. Minerals Engineering 23: 131-1138, doi:10.1016/j.mineng.2010.07.007.

Wahono, S.K., Prasetyo, D.J., Jatmiko, T.H., Suwanto, A., Pratiwi, D., Hernawan, and Vasilev, K. 2019. Transformation of modernite-clinoptilolite natural zeolite of differenet calcination temperature. 2nd International Conference on Natural Product and Bioresources Science. IOP Publishing-IOP Conference Series: Earth and Environmental Science 251(209):012009, doi:101088/1755-1315/251/1/012009.

Wang, S. and Peng, Y. 2010. Natural zeolites as effective adsorbent in water and wastewater treatment. Journal of Chemical Engineering 156:11-24, doi:10.1016/j.cej.2009.10.029.

Zendelska, A., Golomeova, M., Blazev, K., Boev, B., Krstev, B., Golomeov, B. and Krstev, A. 2015. Kinetic studies of manganese removal from aqueous solution by adsorption on natural zeolite. Macedonian Journal of Chemistry and Chemical Engineering 34(1):213-220, doi:10.20450/mjcce.2015.552.


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